LIST OF USES
- TOP
- List of uses
- Light curing sensitizers
Light curing sensitizers
Light curing resins are synthetic resins that chemically change from liquid to solid as a polymerization reaction is started when irradiated with light of a specific wavelength. While they have been used for plate making such as screen printing for a long time, they are still used today in a wide range of applications, including adhesives for electronic materials, resist inks, gel nails, and UV resins for handcraft. The most familiar example of the use of light curing resin is in dental treatment. It is popularly used nowadays to fill teeth that are cut to remove dental cavities, since it can be cured in a short period of approximately 20 seconds by ultraviolet irradiation. In general, curing is done under ultraviolet light (UV) with a wavelength of 200 to 400 nm, but the use of LEDs as light sources has attracted attention in recent years due to their advantages that include longer life, lower operating costs, and lower power consumption. However, it is possible that the mixtures that used to cure under UV will not solidify as expected when UV-LEDs, which have shorter wavelength bands, are used. With this being one of the impacting factors, thiol sensitizers that can cure the resins at a lower energy are attracting renewed attention.
Application example
- Adhesives for electronic materials
- resist Ink
- Chain transfer agents
- Crosslinking agent
- dental Materials
- UV resin for handcraft
Sensitization
measurement conditions:room temperature,Air atmosphere
UV lamp radiation value E(abs): 100[mW/cm2]
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monomer
Trimethylolpropane triacrylate 100parts
-
initiator
1-Hydroxycyclohexylphenylketone 2parts
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sensitizer
TMMP, PEMP, DPMP 0~10parts
Oxygen inhibition restraint
When thiol was used as a sensitizer for a light curing resin, the thin film was completely cured in air without oxygen inhibition, regardless of the olefin species of acrylate and allyl ether. When thiol was not used, curing was inhibited by diffusion of oxygen from the air, and the resin did not cure at all under UV irradiation for 1 minute in the air. Surface tackiness caused by insufficient curing remained even after UV irradiation for 10 minutes.
Completely curing
Completely curing
insufficient curing
insufficient curing(Sticky)
Completely curing
film thickness:5μm UV lamp radiation value E(abs): 2 [mW/cm2] thiols:PEMP
Improved adhesion
test method:Compliant with JIS K6850:1999
Adhesive substrate:PMMA
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monomer
Trimethylolpropane triacrylate 100parts
-
initiator
1-Hydroxycyclohexylphenylketone 2parts
-
sensitizer
TMMP, PEMP, DPMP 5parts
Line up
Product
Structural formula
Viscosity
(mPa・s) [25℃]
TMMP-LV
TMMP-HS
PEMP-LV
PEMP-HS
<10
(50℃)
The values shown above are typical values,not guranteed values.